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This predictability allows the relative abundances of related nuclides to be used as a clock to measure the time from the incorporation of the original nuclides into a material to the present.The basic equation of radiometric dating requires that neither the parent nuclide nor the daughter product can enter or leave the material after its formation.All ordinary matter is made up of combinations of chemical elements, each with its own atomic number, indicating the number of protons in the atomic nucleus.Additionally, elements may exist in different isotopes, with each isotope of an element differing in the number of neutrons in the nucleus.The possible confounding effects of contamination of parent and daughter isotopes have to be considered, as do the effects of any loss or gain of such isotopes since the sample was created.It is therefore essential to have as much information as possible about the material being dated and to check for possible signs of alteration.In these cases, usually the half-life of interest in radiometric dating is the longest one in the chain, which is the rate-limiting factor in the ultimate transformation of the radioactive nuclide into its stable daughter.Isotopic systems that have been exploited for radiometric dating have half-lives ranging from only about 10 years (e.g., tritium) to over 100 billion years (e.g., samarium-147).

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This transformation may be accomplished in a number of different ways, including alpha decay (emission of alpha particles) and beta decay (electron emission, positron emission, or electron capture).

Precision is enhanced if measurements are taken on multiple samples from different locations of the rock body.

Alternatively, if several different minerals can be dated from the same sample and are assumed to be formed by the same event and were in equilibrium with the reservoir when they formed, they should form an isochron. In uranium–lead dating, the concordia diagram is used which also decreases the problem of nuclide loss.

As the mineral cools, the crystal structure begins to form and diffusion of isotopes is less easy.

At a certain temperature, the crystal structure has formed sufficiently to prevent diffusion of isotopes.

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